Fog and rain water chemistry at Mt. Fuji: A case study during the September 2002 campaign   总被引：2，自引：0，他引：2  

Koichi Watanabe  Yusaku Takebe  Nobuhiro Sode  Yasuhito Igarashi  Hiroshi Takahashi  Yukiko Dokiya 《Atmospheric Research》2006,82(3-4):652

Measurements of fog and rain water chemistry at the summit of Mt. Fuji, the highest peak in Japan, as well as at Tarobo, the ESE slope of Mt. Fuji in September 2002. The pH of fog and rain water sampled at Mt. Fuji varied over a range of 4.0–6.8. Acidic fogs (pH < 5.0) were observed at the summit when the air mass came from the industrial regions on the Asian continent. The ratio of [SO₄²⁻]/[NO₃⁻] in the fog water was lower at Tarobo than at the summit. High concentrations of Na⁺ and Cl⁻ were determined in the rain water sampled at the summit, possibly because of the long-range transport of sea-salt particles raised by a typhoon through the middle troposphere. The vertical transport of sea-salt particles would influence the cloud microphysical properties in the middle troposphere. Significant loss of Mg²⁺ was seen in the rain water at the summit. The concentrations of peroxides in the fog and rain water were relatively large (10–105 μM). The potential capacity for SO₂ oxidation seems to be strong from summer to early autumn at Mt. Fuji. The fog water peroxide concentrations displayed diurnal variability. The peroxide concentrations in the nighttime were significantly higher than those in the daytime.  相似文献   

Partitioning of Ni²⁺, Co²⁺, Fe²⁺, Mn²⁺ and Mg²⁺ between olivine and silicate melts: compositional dependence of partition coefficient   总被引：1，自引：0，他引：1  

Eiichi Takahashi 《Geochimica et cosmochimica acta》1978,42(12):1829-1844

Partitioning of Ni²⁺, Co²⁺, Fe²⁺, Mn²⁺ and Mg²⁺ between olivine and silicate melts has been determined near the join (Mg_0.5·-Fe_0.5)₂SiO₄-K₂O 4SiO₂ and for seven different basaltic compositions. The experiments were made at 1 atm total pressure, 1500-1100°C, and under moderate to reducing oxygen fugacities. The concentration factor, defined as K^MO = (MO)^ol/(MO)^liq (molar ratio), increases markedly for all the cations studied as the olivine component of the liquid decreases. Much of the increase in K^MO is considered as due to the compositional effect of the coexisting liquid: the temperature effect on K^MO is probably opposite to the compositional effect (K^MO decreases as temperature decreases).The partition coefficient K^MO-MgO = (MO/MgO)^ol/(MO/MgO)^liq for the reaction, M_ol²⁺ + Mg_liq²⁺ = M_liq²⁺ + Mg_ol²⁺. is relatively constant over a wide range of SiO₂ content of the liquid, except in the case of Ni²⁺. The partition coefficients have similar ranges both in synthetic and natural rock systems: K^NiO-MgO = 1.8–3.0, K^CoO-MgO = 0.6–0.8, K^FeO-MgO = 0.27–0.38, and K^MnO-MgO = 0.23–0.32. There is a systematic variation in the partition coefficient K^MO-MgO with the composition of liquid; K^MO-MgO increases with increasing SiO₂ content of melt. The partition coefficients for Co²⁺, Fe²⁺ and Mn²⁺ are useful to test the equilibration of olivine with magma of a wide compositional range.  相似文献   

Effect of hydrostatic pressure on the lattice parameters of Fe₂SiO₄ olivine up to 70 kbar     

Takehiko Yagi  Yoshiaki Ida  Yosiko Sato  Syun-Iti Akimoto 《Physics of the Earth and Planetary Interiors》1975,10(4):348-354

The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe₂SiO₄ olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K₀ = 1.19 ± 0.10 Mbar and K₀′ = 7 ± 4, and if we assume K₀′ = 5: K₀ = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made.  相似文献   

NATURE OF PRECIPITATION AND ACTIVITY OF CUMULUS CONVECTION DURING THE 1991 MEIYU SEASON OF CHANGJIANG-HUAIHE RIVER BASIN^*     

Lu Er  Ding Yihui  Masato Murakami  Kiyotoshi Takahashi 《Acta Meteorologica Sinica》1998,12(1):75-91

Seasonal variability regarding the nature of precipitation and the activity of cumulus convection during the 1991 Meiyu season of Changjiang-Huaihe River Basin(Jianghuai)has been investigated by calculating apparent heat source/apparent moisture sink and analyzing TBB(cloud-top blackody radiation temperature)data.It is found that three periods of strong ascending motion during the Meiyu season lead to three episodes of heavy rain,and the latent heat due to the precipitation is of the sole heat source of the atmosphere.The nature of precipitation shows distinct seasonal variability,from frontal precipitation of the first episode to the extremely strong convective precipitation of the third episode.TBB field of East Asia may well reflect not only the intensity of convection and rainfall,but also the movement of rain belt and convection belt.In the whole Meiyu season.convection belt mainly stays in Jianghuai.but may shift within the domain of East Asia.Its locating in Jianghuai or not determines the maintenance or break of Meiyu.In the third episode,the narrow convection belt over Jianghuai is mainly caused by southwest monsoon which takes moist and convective atmosphere from tropical ocean.  相似文献   

A new technique for measuring diffusion coefficients of cations and anions in ionic crystals     

Hiroki Sato  Yoshiaki Ida 《Physics of the Earth and Planetary Interiors》1981,25(4):396-405

A new technique has been developed for measuring the diffusion coefficient in ionic crystals. Based on Einstein's formula expressing the relation between diffusion coefficient and electric mobility, the electrical impedance of a diatomic ionic crystal is derived theoretically as a function of frequency of the applied electric field. In this method, the diffusion coefficients of both cations and anions are determined simultaneously by fitting the measured impedance to the theoretical relation. This method was applied to NaCl single crystals in the temperature range 370–780°C. The impedance was determined over the frequency range 0.01 Hz to 1 kHz, at constant temperature. The diffusion coefficients thus obtained for NaCl agree reasonably well with previous data by means of a radioactive isotope technique. The activation energies for Na⁺ and Cl^? obtained are 1.97±0.03 eV and 2.08±0.06 eV, respectively, in the intrinsic region, and 0.92±0.02 eV and 1.06±0.02 eV in the extrinsic region. It was discovered that there are diffusion blocks of approximately 2 μm width, which obstruct free migration of ions in a single crystal.  相似文献   

Clinoamphibole lamellae in diopside of garnet lherzolite from Alpe Arami,Bellinzona, Switzerland     

Yoshiaki Yamaguchi  Junji Akai  Katsutoshi Tomita 《Contributions to Mineralogy and Petrology》1978,66(3):263-270

Porphyroclastic diopside in garnet lherzolite from Alpe Arami, Bellinzona, Switzerland includes optically-visible clinoamphibole lamellae with a composition intermediate between pargasite and edenite. X-ray and electron microscopic observations show that the diopside crystal contains sub-microscopic thin clinoamphibole lamellae parallel to (010), which have coherent interfaces to the host. A kind of planar defect parallel to (010) in clinopyroxene structure, as suggested by Chisholm (1973), is shown here to correspond to intercalation of a 9 Å lattice fringe of double-chain structure in the electron micrograph of the diopside. The thin clinoamphibole lamellae are observed to be segregated domains consisting of two and more 9 Å fringes.From the chemical characteristics and textural relations of the development of such clinoamphiboles, the chemical change required to form them is considered to have been caused principally by decreasing solubility of atoms such as Na, Al and Cr in clinopyroxene structure during the retrogressive reequilibration. Also, a possibility of finite solid solution of clinoamphibole in clinopyroxene is discussed.  相似文献   

Temporal changes in thermal waters related to volcanic activity of Tokachidake Volcano,Japan: implications for forecasting future eruptions     

Ryo Takahashi  Tomo Shibata  Yasuji Murayama  Tagiru Ogino  Noritoshi Okazaki 《Bulletin of Volcanology》2015,77(1):1-12

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Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal   总被引：4，自引：4，他引：0  

Akihiro Hachikubo  Oleg Khlystov  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Shin’ya Nishio  Masato Kida  Takao Ebinuma  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):321-329

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.  相似文献   

Discrimination of spurious self-correlation in nondimensionalized analyses of fluid dynamical data     

Yoshiaki Toba  Naoya Suzuki  Satoru Komori 《Journal of Oceanography》2008,64(3):393-397

Nondimensionalization of variables enables us to treat experiment data much more simply and efficiently by decreasing the number of variables. In some cases, trivial conclusions (which Kenney, 1982, called spurious self-correlation) result from a formal application of dimensional analyses. In contrast, in some cases fully significant conclusions can be derived. We first discuss how to construct nondimensional variables retaining the physical meanings of variables. We then propose simple and efficient methods, especially the use of “spurious triangle (SpT)”, to discriminate between significant conclusions and spurious self-correlations in the analysis of nondimensionalized variables.  相似文献   

Modeling Arctic Ocean heat transport and warming episodes in the 20th century caused by the intruding Atlantic Water     

Jun Takahashi  Tatsuo Suzuki  Igor V Polyakov  Kohei Mizobata  Moto Ikeda  Fancois J.Saucier  Markus Meier 《极地研究(英文版)》2008,19(2):159-167

This study investigates the Arctic Ocean warming episodes in the 20th century using both a high-resolution coupled global climate model and historical observations. The model, with no flux adjustment, reproduces well the Atlantic Water core temperature （AWCT） in the Arctic Ocean and shows that four largest decadalscale warming episodes occurred in the 1930s, 70s, 80s, and 90s, in agreement with the hydrographic observational data. The difference is that there was no pre-warming prior to the 1930s episode, while there were two pre-warming episodes in the 1970s and 80s prior to the 1990s, leading the 1990s into the largest and prolonged warming in the 20th century. Over the last century, the simulated heat transport via Fram Strait and the Barents Sea was estimated to be, on average, 31.32 TW and 14.82 TW, respectively, while the Bering Strait also provides 15.94 TW heat into the west- ern Arctic Ocean. Heat transport into the Arctic Ocean by the Atlantic Water via Fram Strait and the Barents Sea correlates significantly with AWCT （ C = 0.75 ） at 0- lag. The modeled North Atlantic Oscillation （NAO） index has a significant correlation with the heat transport （ C = 0.37 ）. The observed AWCT has a significant correlation with both the modeled AWCT （ C =0.49） and the heat transport （ C =0.41 ）. However, the modeled NAO index does not significantly correlate with either the observed AWCT （ C = 0.03 ） or modeled AWCT （ C = 0.16 ） at a zero-lag, indicating that the Arctic climate system is far more complex than expected.  相似文献